Saturday, August 29, 2015

Lavender Chemistry

Lavender distillation

CHEMICAL CONSTITUENTS of LAVENDER
Some 300 molecules were discovered in true lavender's essential oil, that are responsible for its fine, complex yet clear aroma - most of which are trace elements. The major constituents are (the ones in bold are the most dominant/famous ones):
Linool
Linalyl acetate (up to 40%) 
Lavandulol *
Lavandulyl acetate *
Cineole
Coumarin
Camphor
1-octen-3-yl acetate
Tricyclene  
alpha-Pinene  
alpha-Thujene  
Camphene  
beta-Pinene  
Sabinene  
gamma-Terpinene  
Myrcene  
alpha-Terpinene  
5-Methyl-3-heptanone  
Limonene  
Eucalyptol  
delta-3-Carene  
(E)-beta-Ocimene  
Octan-3-one  
para-Cymene  
Terpinolene  
Hexyl-isobutyrate  
Neo-allo-ocimene  
3-Acetoxy-octene  
Hexyl-butyrate  
cis-Linalool oxide  
Vinyl amyl carbinol  
trans-Linalool oxide  
Camphor
Dihydrolinalool  
(E)-Caryophyllene  
Terpinen-4-ol  
(E)-beta-Farnesene  
alpha-Terpineol  
Borneol  
Neryl acetate  
Geranyl acetate  
Nerol  
Geraniol  
Caryophyllene oxide  
alpha-Humulene  
Hexyl acetate  
alpha-Santalene

As we can see, it mostly contains terpenes, terpene alcohols and esters, and a few alcohols. According to Jeanne Rose "esters are soothing, calming, and fungicidal"; and linalool is an "antibacterial, believes discomfort, diuretic, tones without irritating, stimulates the immune system, sedating"; the latter actions similarly described as initiated by the terpene alcohols as well as toning (The Aromatherapy Book, pp. 158-160).

* Both lavandulol and lavandulyl acetate are insect pheromones, which might explain the abundance of bees observed around lavender shrubs.

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